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Lampeka Yaroslaw

Lampeka Yaroslaw

Doctor hab., Professor in Inorganic Chemistry

Leading Research Scientist

Телефон: tel. +38 (044) 525-65-40
Email: lampeka@adamant.net

Scientific interests

General: Chemistry of coordination compounds.

Main directions: Synthesis, spectral and redox properties of transition metal complexes with polydentate (including azamacrocyclic) ligands, structure of coordination compounds is solution and in crystalline state, study of kinetic features and mechanisms of redox reactions of coordination compounds; metal-organic frameworks, their adsorption properties; supramolecular chemistry, host-guest interactions

Professional experience

Years

Position

1971-1976

Student at the Chemistry Department of T.Shevchenko Kiev National University

1976-1979

Post-graduate student at L.V.Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine

1981-1983

Junior Research Scientist at the same Institute

1984-1998

Senior Research Scientist at the same Institute

since 1999

Leading Research Scientist at the same Institute

Education

Kiev National University of T.Shevchenko, Chemistry Department

Ph.D.Thesis -1980 (L.V.Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of UkrRSR).

Doctor of Sciences Thesis -1999 (L.V.Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine).

Author of one monograph, 4 patents, more 120 scientific publications

Awards

-        The State Award of Ukraine in the Area of Science and Technology (1991) and L.V.Pisarzhevskii Award of the National Academy of Sciences of Ukraine (1997)

Scientific cooperations

Prof. Р. Comba, Dr. H. Pritzkow, Anorganisch-Chemisches Institut, Universitat Heidelberg (Germany)

Prof. R. W. Hay, Dr. Ph. Lightfoot, School of Chemistry, University of St. Andrews (UK)

Prof. J. Taraszewska, Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

Prof. V. Arion, Institute of Inorganic Chemistry, University of Vienna (Austria)

Dr. Е. Кashuba, Karolinska Institute, Stockholm (Sweden)

List of selected publications

1. Gavrish S.P., Lampeka Ya.D., Lightfoot P., Pritzkow H. The crystal and molecular structures of the related nickel(II) complexes of open-chain and macrocyclic oxamide-based ligands and the peculiarities of water aggregates in their crystal lattices, Dalton Trans.- 2007.- N41.- P. 4708 - 4714.

2. Comba, P., Lampeka Ya.D., Prikhod’ko A.I., Rajaraman G. Determination of the solution structures of melamine-based bis- and tris-macrocyclic ligand copper(II) complexes, Inorg. Chem., 2006, v. 45, N 9, p. 3632-3638.

3. Atanasov M., Comba P., Lampeka Ya.D., Linti G., Malcherek T., Miletich R., Prikhod’ko A.I., Pritzkow H. Encapsulation of cyanometalates by a tris-macrocyclic ligand tricopper(II) complex: syntheses, structural variation, and magnetic exchange coupling pathways, Chem. Eur. J. 2006, v.12, N3, p.737 – 748.

4. Gavrish S.P., Lampeka Ya.D., Lightfoot P. Solution properties of the nickel(II,III) and copper(II,III) complexes of trans-dioxocyclam (trans-dioxocyclam=5,12-dioxo-1,4,8,11-tetraazacyclotetradecane) and the X-ray crystal structure of the N-rac-isomer of the nickel(II) complex, Inorg. Chim. Acta, 2004, v.357, N4, p.1023-1030.

5. Comba P., Kerscher M., Lampeka Ya.D., Lötzbeyer L., Pritzkow H., Tsymbal L.V. Structural properties of cyclopentanone-bridged bis-macrocyclic ligand dicopper(II) complexes in the solid and in solution: a successful test of the MM-EPR method, Inorg. Chem., 2003, v.42, N11, p.3387-3389.

6. Comba P., Lampeka Ya.D., Lötzbeyer L., Prikhod´ko A.I. Macrocyclic melamine-based ligand complexes as building blocks for the metal-directed synthesis of heterometallic di- and trinuclear compounds, Eur. J. Inorg. Chem., 2003, N.1, p.34-37.

7. Comba P., Lampeka Ya.D., Nazarenko A.Y., Prikhod´ko A.I., Pritzkow H., Taraszewska J. Cooperative effects in the binding of substrates to nickel(II) and nickel(III) complexes with a bis(macrocyclic) ligand, Eur. J. Inorg. Chem., 2002, N7, p.1871-1882

8. Comba P., Lampeka Ya.D., Nazarenko A.Y., Prikhod´ko A.I., Pritzkow H. Interactions between copper(II) complexes of mono-, bis- and tris(macrocyclic) ligands and inorganic or organic guests, Eur. J. Inorg. Chem., 2002, N6, p.1464-1474.

9. Tsymbal L.V., Lampeka Yа.D., Taraszewska J. Synthesis and spectral properties of new bis(macrocyclic) nickel complexes and the influence of their structure and medium on electrochemical behavior, Polyhedron, 2001, v.20, N 15-16, p 1837 – 1844.

10. Hansen L., Lampeka Ya.D., Gavrish S.P., Xu X., Taylor A.T., Marzilli L. Re(V) complexes with an open-chain quad­ridentate ligand containing two amine and two amido donors. Synthesis, characterization, and solution equilibria of Re2O3(dioxo-tetH4)2 and [ReO(H2O)(dioxo-tetH4)]Cl (dioxo-tetH6 = 1,4,8,11-tetraazaundecane-5,7-dione), Inorg. Chem., 2000, v.39, N25, p.5859-5866