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MainDEPARTMENTSLABORATORY OF SPECTROSCOPY OF POLYMERSPavlishchuk Vitaly V.

Pavlishchuk Vitaly V.

Pavlishchuk Vitaly V.

Corresponding Member of the National Academy of Sciences of Ukraine, Doctor of Chemistry (habilitat), Professor of Inorganic Chemistry

Deputy Director of the Institute on Scientific Affairs and the Laboratory Head

Телефон: +(380) 44 525 42 28
Факс: +(380) 44 525 62 16
Email: shchuk@inphyschem-nas.kiev.ua

The area of main scientific interests: physico- inorganic chemistry,  in particular:

the theory of chemical structure in coordination compounds;

the molecular magnetism of 3d- і 4f- metal polynuclear complexes;

processes with electron transfer: the electrochemistry of coordination compounds, kinetics and mechanisms of inorganic reactions;

physical chemistry of magnetic nanoparticles;

Professional records

Years

                                            Position

1978-1981

 

Ph.D. student in  L.V.Pisarzhevskii Institute of Physical Chemistry of the Academy of Sciences of UkrSSR

1981-1987

 

Junior research scientist  in the same Institute

1987-1990

 

Research scientist  in the same Institute

1990-1995

 

Senior research scientist  in the same Institute

1992-1996

 

Scientific Secretary L.V.Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine

1996-2003

 

Leading research scientist  in the same Institute

2003 р.-

 

The Laboratory Head  in the same Institute

2003 р.-

 

Deputy Director of the Institute on Scientific

Education

graduated from T.G. Shevchenko State University, Department of Chemistry (1978)

Ph.D. studentship in L.V.Pisarzhevskii Institute of Physical Chemistry of the Academy of Sciences of UkrSSR (1978-1981)

Ph.D. (Inorganic Chemistry) – L.V.Pisarzhevskii Institute of Physical Chemistry of the Academy of Sciences of UkrSSR, 1982

Postdoctoral Fellowship in Drexel University, Philadelphia, PA (group of Dr A.W. Addison) 1990-1991

Doctor of Chemistry (habilitat in Inorganic Chemistry)- 1995

Professor (Inorganic Chemistry) - 2004

Scientific Awards

State Prize Prize of the Ukraine in the field of Science and Technology (2007), L.V.Pisarzhevskii Prize of the National Academy of Sciences of Ukraine (1997).

Elected as the Corresponding Member of the National Academy of Sciences of Ukraine, specialty – physic-inorganic chemistry - 2009.

Scientific ties

Department of Chemistry Drexel University, Philadelphia, PA (group of Dr A.W. Addison) – according to Agreement about collaboration in the field of physical chemistry of polynuclear complexes;

The Laboratory of Solid State Chemistry of CNRS, Rennes, France – Prof. L. Ouahab- grants within the Agreement on cooperation between the NAS of the Ukraine and CNRS- studies of magnetism of polynuclear complexes and nanoparticles.

Department of Chemistry of Memorial University, Canada-Prof. L. Thompson – molecular magnetism of polynuclear complexes;

N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow- academician V.М.Novotortsev and І.L.Yeremenko- studies of molecular and crystal structure of polynuclear complexes. 

Selected  publications

  • Pavlishchuk V. V., Kolotilov S. V., Addison A. W., Prushan M. J., Butcher R. J.,  Thompson L. K. Mono- and Trinuclear Nickel(II) Complexes with Sulfur-Containing Oxime Ligands: Uncommon Templated Coupling of Oxime with Nitrile. Inorg. Chem. 1999, v. 38(8), pp. 1759-1766.
  • Pavlishchuk, V. V.;  Koval, I. A.; Goreshnik, E. A.; Addison, A. W.; van Albada G. A; Reedijk J. The First Example of a True ‘‘Turnbull’s Blue’’ Family Compound with Trapped Iron Oxidation States. Eur. J. Inorg. Chem. 2001 , 297-301.
  • V.V. Pavlishchuk, S.V. Kolotilov, A.W. Addison, M.J. Prushan,  D. Schollmeyer, L.K.Thompson, E.A.Goreshnik A Tetrameric Nickel (II) "Chair" with both Antiferromagnetic Internal Coupling and Ferromagnetic Spin Alignment Angew. Chem. Int. Ed. 2001, 40, No. 24, 4734-4737.
  • V.V. Pavlishchuk, S.V. Kolotilov, A.W. Addison, M.J. Prushan, R.J. Butcher, L.K. Thompson A New Class of Macrocyclic Complexes Formed via Nickel-Promoted Macrocyclisation of Dioxime with Dinitrile Chem. Commun. 2002, P.468-469.
  • Gavrilenko K.S., Vértes A., Vanko G., Kiss L.F., Addison A.W., Weyhermüller T.,  Pavlishchuk V.V., Synthesis, magnetochemistry and spectroscopy of heterometallic trinuclear basic acetates [Fe2M m3-O(CF3COO)6(H2O)3] · H2O (M = Mn, Co, Ni), Eur. J. Inorg. Chem., 2002, 2002(12), 3356-3363.
  • Pavlishchuk, V. V.; Birkelbach, F.; Weyhermüller, T.; Wieghardt, K.; Chaudhuri, P. Polynuclear Complexes of the Pendent-Arm Ligand 1,4,7-Tris(acetophenoneoxime)-1,4,7-triazacyclononane Inorg. Chem. 2002, 41, 4405-4416
  • V. V. Pavlishchuk, S. V. Kolotilov, A. W. Addison, M. J. Prushan, D. Schollmeyer, L. K. Thompson, T. Weyhermüller, E. A. Goreshnik Structural, magnetic and related attributes of some oximate-bridged tetranuclear nickel(II) rhombs and a dinuclear congener J. Chem. Soc., Dalton Trans. 2003, P. 1588-95.
  • V.V.Pavlishchuk Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol: formation of coordinated phenoxyl radical Inorg. Chem. Comm., 2005, 8, 10, 932-935
  • Gavrilenko K.S., Punin S.V., Cador O., Golhen S., Ouahab L., Pavlishchuk V.V. Synthesis, Structure, and Magnetism of Heterometallic Carboxylate Complexes [MnIII2MII4O2(PhCOO)10(DMF)4], M = MnII, CoII, NiII, Inorg. Chem., 2005, 44(16), 5903-5910.
  • Gavrilenko K.S., Punin S.V., Cador O., Golhen S., Ouahab L., Pavlishchuk V.V. In situ generation of carboxylate: an efficient strategy for a one-pot synthesis of homo- and heterometallic polynuclear complexes, J. Am. Chem. Soc., 2005, 127(35), 12246-12253. 
  • R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, O. Cador, S. Golhen, O. V. Shvets, L. Ouahab, Z. V. Dobrokhotova, V. I. Ovcharenko, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk Structural flexibility and sorption properties of 2D porous coordination polymers constructed from trinuclear heterometallic pivalates and 4,4'-bipyridine Eur. J. Inorg. Chem., 2011, 4985–4992.
  • E. A. Mikhalyova, S. V. Kolotilov, O. Cador, M. Zeller, S. Trofimenko, L. Ouahab, A. W. Addison, V. V. Pavlishchuk, A. D. Hunter The role of the bridging group in exchange coupling in dinuclear homo- and heterometallic Ni(II) and Co(II) complexes with oxalate, oxamidate and dithiooxamidate bridges Dalton Trans., 2012, 41 (37), 11319 – 11329.
  • E. A. Mikhalyova, S. V. Kolotilov, M. Zeller, L. K. Thompson, A. W. Addison, V. V. Pavlishchuk, A. D. Hunter Synthesis, structure and magnetic properties of Nd3+ and Pr3+ 2D polymers with tetrafluoro-p-phthalate Dalton Trans. 2011, 40, 10989–10996.
  • R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, O. Cador, E. A. Mikhalyova, A. S. Lytvynenko, S. Golhen, L. Ouahab, V. I. Ovcharenko, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk Topology Control of Porous Coordination Polymers by Building Block Symmetry, Eur. J. Inorg. Chem., 2010, 5055–5057