На главную
Русский Українська

9


Teoret. i eksperim. khimiya. 2004. Vol.40 No. 2. p. 116-119

Interaction of Methane and Oxygen with the Surface
of Oxide Manganese-Containing Catalysts

 

E. V. Bezrukov, L. N. Kurina*


Institute of Chemistry of Petroleum, Siberian Branch of Russian Academy of Sciences
3 Prosp. Akademichesky, 634021 Tomsk, Russian Federation. E-mail: ewbezrukov@mail.ru

* Tomsk State University
36 Prosp. Lenina, 634050 Tomsk, Russian Federation


Interaction of methane and oxygen with the surface of oxide manganese-containing catalysts was studied by pulse reduction and temperature-programmed oxidation. It was supposed that in the process of oxida- tive dimerization of methane the phase, supplying strong-bonded oxygen for selective combination of methane, is an acceptor of weak-bonded oxygen in the phase, which catalyzes deep oxidation.


Key words oxidative dimerization of methane, manganese oxide, sodium silicate, oxygen, methane.