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10


Teoret. i eksperim. khimiya. 2004. Vol.40 No. 3. p. 181-185

Catalytic Properties of (Fe, Al)-MCM-41
in CO and Light Alkanes Conversion with Participation of Nitrogen Oxides

 

S. N. Orlyk, G. Pop*, R. Ganea*, V. A. Ostapyuk, L. M. Alekseenko


L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine
31 Prosp. Nauky, 03028 Kyiv, Ukraine. E-mail: orlyk@inphyschem-nas.kiev.ua

* S.C. ZECASIN S.A
Romania, 77208 Bucharest, Spl. Independentei 202 - Sector 6


Synthesized mesoporous material (Fe, Al)-MCM-41 was characterized by the methods of XRD, IR, XP, and NMR spectroscopy. Catalytic activity of the (Fe, Al)-MCM-41 in reactions with participation of nitrogen oxides, in particular, partial oxidation of propane with nitrogen(I) oxide to isopropyl alcohole, results from definite combination of structural, acidic and oxidativeñreductive properties of the surface.


Key words mesoporous iron-containing material, structural, acidic and oxidative-reductive properties of the surface, re-
actions with nitrogen oxides participation.