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Teoret. i eksperim. khimiya. 2004. Vol.40 No. 5. p. 298-301

Kinetics of Conversions of Peroxynitrous Acid
in Reactions of Isomerization, Decomposition, and Reduction by Cyclohexane


V. P. Tretyakov, L. A. Minko, E. S. Rudakov

L. M. Litvinenko Institute of Physical-Organic and Coal Chemistry, National Academy of Sciences of Ukraine
70 R. Luxemburg Vul., 83114 Donetsk, Ukraine. E-mail: rudakov@esrud.donetsk.ua

The kinetics of decomposition and reduction of HOONO by cyclohexane in the aqueous solutions were studied. The measured effective rate constants of the reactions are used for comparison of the acid reac- tivities in the processes of isomerization, decomposition, and reduction.

Key word kinetics, peroxynitrous acid, isomerization, decomposition, reduction, cyclohexane, oxidation.