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10


Teoret. i eksperim. khimiya. 2006. Vol.42 No. 1. p. 55-60

Effect of the Structure of the Copper(II) Complexes Adsorbed on the Surface of SiO2
on Their Catalytic Activity in Decomposition Reaction of Ozone

 

T. L. Rakitskaya, A. S. Truba, L. A. Raskola, A. Yu. Bandurko, A. A. Golub*


I. I. Mechnikov Odesa National University
Vul. Dvoryanska 2, 65026 Odesa, Ukraine. Е-mail: truba@onu.edu.ua

* Taras Shevchenko Kyiv National University
Vul. Volodymyrska 60, 01033 Kyiv, Ukraine. Е-mail: agolub@chem.univ.kiev.ua


The composition, structure, and catalytic activity in the reaction of ozone decomposition of copper(II) complexes with acidoligands and Schiff bases (benzaldiminepropyl derivatives) anchored to silica (silica gel, aerosil) was described; the methods to control their catalytic activity were shown.


Key word ozone, complexes, Schiff bases.