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Teoret. i eksperim. khimiya. 2006. Vol.42 No. 1. p. 39-43

Influence of the Structure of Bridging Ligands on the Structure and Sorption Properties
of 3D-Coordination Polymers Based on Copper(II) and Cobalt(II) Formates


S. V. Kolotilov, O. V. Shvets, V. M. Solomakha

L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine
Prosp. Nauky 31, 03028 Kyiv, Ukraine. E-mail: svk001@mail.ru

It was shown that the increase of the length of bridging ligands - pyrazine analogues - results in forma- tion of microporous coordination polymers. The structure of one of the compounds was determined by Rietveld method. The difference in sorption capacity of the obtained compounds on methanol, nitrogen and hydrogen was found.

Key word porous coordination polymers, Rietveld method, methanol sorption, hydrogen sorption.