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Teoret. i eksperim. khimiya. 2006. Vol.42 No. 2. p. 113-118

Influence of Nitrogen Oxides NOx on the Gas-Phase Oxidation of Methane by Oxygen


Yu. I. Pyatnitsky

L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine
Prosp. Nauky 31, 03028 Kyiv, Ukraine. E-mail: yupyat@fm.com.ua

The kinetic model of the gas-phase oxidation of methane by oxygen was proposed. The calculations based on the model were in satisfactory accordance with the kinetic experimental data presented in literature. The principal reasons of nitrogen oxide influence on reaction rate and selectivity to methanol and formaldehyde were discussed.

Key word oxidation of methane, formaldehyde, methanol, nitrogen oxides, kinetic model.