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5


Teoret. i eksperim. khimiya. 2007. Vol.43 No. 1. p. 43-46

Effect of the Fractal Dimension of the Porous Catalyst
on the Activation Energy in the CO Oxidation

 

A. I. Tripolsky, P. E. Strizhak


L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine
Prosp. Nauky, 31, Kyiv 03028, Ukraine. E-mail: pstrizhak@hotmail.com


By the example of reaction of the CO oxidation we introduce a new approach establishing a relationship between the activation energy of the limitative stage of the heterogeneous catalytic process and fractal di- mension of a catalyst. It is shown that activation energy of the process increases with increasing the fractal dimension of a catalyst, i.e. with grow spatial inhomogeneity of a catalyst.


Key word catalyst, fractal dimension, kinetics, activation energy.