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Teoret. i eksperim. khimiya. 2007. Vol.43 No. 1. p. 47-51

Influence of the Structure of Crystal Lattice
of the Nickel(II) Complex with Amide-Containing Ligand
on Its Stability and Adsorption Properties


S. P. Gavrish, Ya. D. Lampeka, P. S. Yaremov, V. G. Ilyin

L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine
Prosp. Nauky, 31, Kyiv 03028, Ukraine. E-mail: lampeka@iphch.kiev.ua

The crystal lattice of the hydrate of the nickel complex with tetradentate amide-containing ligand is built from hexamers of metall complex units connected by intermolecular hydrogen bonds which remain during ad(de)sorption of polar molecules. Some lability is inherent in the lattice of the material that mani- fests itself in interaction with methanol.

Key word nickel(II), amide-containing ligand, porous materials, dehydration, adsorption properties.